Apart from the electrical issues, we assume this is an early W211 model, will be fitted with the SBC braking system that MB used on this model and i believe some S/SL class too, system dropped at facelift around 06.
Its an electrical hydraulic pump system that pressurises the brakes instead of a normal vacuum servo, the problem being it has a limited number of lives (brake applications) and once its exhausted those it should be changed or you will find massively reduced (circa 10% of normal if my memory serves) brakes available, its a £1500 job i believe.
There are serious dangers when DIYing brakes with this system so do not touch the brakes till you learn how to disable it.
Early 211's weren't galvanized so look carefully for corrosion, i'd spend more time underneath than up top checking it, if it needed brake pipes already its possible the salt wasn't washed off after winters.
Not trying to put you off, still a lovely car and so long as you're aware of what might need doing, bought well is a fine car in its own right.
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