Thanks everyone for your contributions. I'm pleased to say that the offending tyre is still holding up and I've been driving the car to work every day since the incident - with no further deflation or reduction in pressure.
I'm pretty sure it wasn't someone with a grudge who let the tyre down (I park in a secure section of a university staff-only car park - with barrier entry and security point) and I can't imagine any of my colleagues - mainly senior professors getting up to mischief! :-)
A couple of you mentioned valve grit, or damage. Its possible - I have occasionally hit a kerb while reversing - so may have impacted the valve part at some stage. In the garage the guys were thorough with the pressure and leak tests - but nothing new was fitted - otherwise they wouldn't have let me drive out of there without paying a penny ;-)
I think I'll pick up a can of sealant at the weekend. If I notice any more deflation or pressure reduction in the same tyre over the next week or so, I'll take the wheel off and apply sealant lightly between the tire/wheel interface on both sides. Will post message again in any case.
Thanks all!
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