From about 2006 they are supposed to be galvanized, however the C class you refer to was replaced in 2008 and the new model i would happily buy.
E class was extensively revised at facelift point again about 2006, but check any car you are interested in is indeed a facelift and not an earlier car regd a long time after build.
Indeed facelift W211 E class is recognised as being a very good car indeed, not only from corrosion, but thelectrical problems the earlier cars suffered with were sorted, and more importantly the idiot SBS braking system of the pre facelift cars was dropped.
You could do far worse than find yourself a late as possible W 211 E 220CDi, a private hire owner i know usually sells his on when they clock over 400k with very little if any trouble at all, though exceptionally maintained, or a 08 on C Class.
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