a good place to start is the EGR valve equally it could be just a perished hose on the vacuum side,
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The D5 motors have a complex vacuum system, which includes vacuum-actuated engine moutings. As Collos suggests, I would remove the engine cover and look for any of the black rubber vacuum hoses that may have become kinked, trapped or popped off its connector.
Have you got a 'service needed' or other warning light on the dash? It could also be the diesel filter needing a change. Apparently the D5 motors are sensitive to this.
Have a search through the Volvo owner's forum, that may help: www.volvoforums.org.uk/forumdisplay.php?f=113
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