As a rental car it will probably have had basic servicing at the recommended intervals, to keep within the terms of the maker's warranty, at least within that period. Typically when the warranty ends, the car's first MoT becomes due, so it is possible that servicing coincided with those, but don't bank on it.
Many makers - I think Peugeot is one of them - keep computerised service records for cars maintained by their franchised dealers, so try that line of enquiry. If the car has no paperwork or warranty servicing record, you may be on a wild goose chase.
The 207SW I have owned since 2008 had been a rental car for its first 13K miles. I bought it from a Pug dealer who serviced it before sale, but the warranty record had no stamp in the first service box, just a sticker saying that T&C's had been complied with. The car has given me no trouble for 13 years, so I may have been lucky.
What do you consider to be 'anything major' ? I doubt there is any such thing listed beyond regular oil and filter changes at 7 years and 50K miles. Cambelt won't fall due until 100K, and discs and pads will be 'as required'.
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