[1] if you are on a cambered road the car will normally tend to fall gently towards the kerb. If you think your 'problem' may be something else, you could ask your garage to check the tracking. It's not a bad idea to do that from time to time, especially if you suffer a lot from speed bumps or potholes.
[2] I have no experience with electronic measurement of tyre pressure, but I doubt it is as accurate as a direct-measurement gauge. Pressure will normally rise by a few psi (or fraction of a bar) as tyres warm up with driving. Differences between the wheels may reflect differences between the 4 sensors, or that the sunny side shows warmer tyres. If the readings are about right, don't worry. Outdoor temperature also has a noticeable effect.
[3] 'potential leak' ? If the pressures stay from day to day, that is all you need. If you notice a steady fall of 2 psi or more per week, there may be a slow puncture (e.g.nail in tyre) or if the tyres are years old the leak may be round the rim of the wheel. Tyres always have potential for a leak, but that doesn't often happen.
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