I have no scientific basis for this, only what I've read (maybe here/another forum/?):
As most people are aware, if you leave your car out in the sun, it'll get baked like an oven/greehouse. When you open the doors, it'll be MUCH hotter than outside, hence why you should always open all doors first before setting off to purge as much hot air as possible. Even though the air temperature would've dropped considerably, the inner surfaces will still be hot (heated directly by radiative heat from the sun), so drive along (if safe/secure to do so and not raining!) with all your windows open for the first few minutes for speeds up to 30mph or so (drag >30mph costs more fuel than A/C). The hot inner car surfaces will lose heat via the air blowing across them (similar to a person, but without the moisture evaporation).
Once over 35mph for prolonged period and/or inside tempertaure not dropping/surfaces not getting any cooler, shut all windows and use the A/C. My tip is to not set the temp dial too low (say 20-21C) for very high ambient temperatures (26C and above), but for the first 10-20 mins set the temp ~23 and gradually lower it as the journey progresses to lessen the effects of "thermal shock" (going from a hot to a cool environment), which may also have the added effect of giving you a very dry throat.
Seems to work well for me! I also (other than trying to park my car in a shady spot [afternoon shade is best] without being under a lime tree or one full of bird/with lots of bird c**p on the ground) open all the doors of my car for a couple of minutes during my lunch break to help purge as much hot air as possible to lessen the heating affect later on. Have a go and see how you get on.
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