They make a big difference to CO2 figures... it's not just about fuel.
I travel back and forth a lot to the UK, so I get to hire lots of cars, and have some experience of most of the different mainstream stop-start systems.
Firstly, it takes about a day to get used to the system working... in fact going back to a non stop-start car takes more getting used to!
In general they are all intelligent enough to cope with real-world driving, so they don't just keep tabs on aircon load, and keep the PAS running, etc - but also monitor the important things like brake servo vacuum, so you don't find yourself stranded at the top of a steep hill without powered brakes!
The VAG system that I've used in Audi A3s and A4s along with the VW Passat Greenline is the most intuitive I've used, and becomes second nature in no time. The engine stops in a logical way, without any fuss, it's a consistent experience, and can work out from gear position, clutch, brakes and general timing the occasions when you don't want it to kick in such as parking up.
The other extreme are systems like the Hyundai / Kia... the system is eager to kick in when you are still doing about 3mph, the engine then dies with a chug which makes you think you've stalled it (not intuitive), and takes a fraction of a second longer than the VAG system to restart (the VAG cars seem to be running before you've 50% dipped the clutch vs already selecting a gear with the others).
Of course, yes, these are all hire cars with <10k on the clock. How well they work with a duff battery, low compression and stagnant oil in 8-10 years time after 5 owners may be entirely different. But the theory is good! ;)
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