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Citroen Berlingo - Old ad-blue fluid - Dave N
I understand ad blue has a ‘use by’ date on the containers. But what about ad blue that’s been in the car for a while? I ask because I don’t do many miles, although they are long trips, as a result I hardly use any ad blue. As the tank is quite large, the stuff has been in there for quite some time. I last topped it up a good couple of years ago.

Is there anything I should do about it?
Citroen Berlingo - Old ad-blue fluid - paul 1963

What a good question! I don't know the definitive answer but I do know ad blue is something like 60% distilled water so I guess it could evaporate from the tank?

If your really worried you could always drain the tank and refill with fresh, absolutely no idea if that's easy or possible.....

Citroen Berlingo - Old ad-blue fluid - elekie&a/c doctor
I would think that 12-18 months is a reasonable shelf or storage life for adblue . If tank hasn’t been emptied for a couple of years, then it may be an idea to get it flushed before excess sulphation takes place . Unfortunately there is no easy way to drain an adblue tank . It needs to be removed from the ca r. With such low mileage covered , perhaps you’d be better off with a petrol car .
Citroen Berlingo - Old ad-blue fluid - Dave N
Diesel was the only option on the base model van, unfortunately. Could have moved up to a posher model with the pure tech, but in hindsight I may have dodged a bullet there.
Citroen Berlingo - Old ad-blue fluid - paul 1963

Nothing wrong with a diesel Berlingo, my work van is currently on 98k and despite having only 75bhp still go's well.

Citroen Berlingo - Old ad-blue fluid - RichardW

PSA have drain plugs on their ad blue tanks.... they must have forseen that they would need to be changed on a frequent basis!

You can't have sulphation of ad blue - there's no sulphur in it!

Citroen Berlingo - Old ad-blue fluid - elekie&a/c doctor
Crystallise rather than sulfation . Look at the mess it makes when it gets spilled in the boot .
Citroen Berlingo - Old ad-blue fluid - Andrew-T
Crystallise rather than sulfation . Look at the mess it makes when it gets spilled in the boot

IIRC the main ingredient in Adblue is urea. While that doesn't sound nice, it is a fairly simple and harmless organic compound which (obvs) can be flushed away with water.

Citroen Berlingo - Old ad-blue fluid - paul 1963
Crystallise rather than sulfation . Look at the mess it makes when it gets spilled in the boot

IIRC the main ingredient in Adblue is urea. While that doesn't sound nice, it is a fairly simple and harmless organic compound which (obvs) can be flushed away with water.

Your quite right Andrew urea is a ingredient of ad blue but it's mainly distilled water, it does however irritate the skin, I managed to get some down my leg, brought me out in a rash.

Citroen Berlingo - Old ad-blue fluid - Dave N
Just an update. I bought some snake oil that claims to prevent crystals and dumped it in the tank. I tried to syphon out any remaining adblue, but without success. I put in 10 litres of fresh adblue, and called it job done. Its a bit of a pain not knowing the level in the tank, then I could have bought the right amount to fill it up properly.
Citroen Berlingo - Old ad-blue fluid - Andrew-T
I bought some snake oil that claims to prevent crystals and dumped it in the tank. I tried to syphon out any remaining adblue, but without success. I put in 10 litres of fresh adblue, and called it job done. Its a bit of a pain not knowing the level in the tank, then I could have bought the right amount to fill it up properly.

As said above, Adblue is a strong solution of urea in water. The urea is the important ingredient but as it is a solid it has to be in solution to be metered into the fuel system. Over time, in a tank which can easily get quite warm, the water will tend to evaporate leaving urea crystals. I guess the delivery system could get blocked if precautions are not taken ? But as its is an aqueous solution the system can easily be flushed with water with no worries about the urea, a natural organic compound.

Citroen Berlingo - Old ad-blue fluid - gordonbennet
Sometimes if clumsy blighters spill adblu over the bulk pump handle, it crystalises enough to stop the pump handle operating, a kettle of hot water over it shifts it all in no time.