The pumps accurately measure volume, no difference hot or cold - but the fuel expands as it gets warmer so a litre of cold fuel will weigh more than a litre of warm fuel and contain more energy.
As fuel tanks are underground at filling stations, the effect of climate is small but it is better to refuel in the morning, theoretically at least.
As an aside, modern pumps are a lot more accurate than Trading Standards require so they're usually set to take advantage of the permitted tolerance - that's taking advantage from the filling station's point of view, not the customer!
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