I'm running FF with Windows 7 ultimate. No problems, apart from the damn adverts.
If you want to get rid of webpage ads, I would suggest you use the 'Adblock Plus' Add-on and its Pop-up add-on as well (both very highly rated)- they work very well and get rid of almost all ads and unwanted pop-ups (you can tweak both to suit for certain websites). Firefox has IMO the best range of useful add-ons, even if its not quite as fast as Chrome.
I feel very sorry for anyone running Windows Vista (similarly a few years ago for Windows ME users) - unfortunately there comes a time to bite the bullet and change to a better OS. Not sure about Windows 10 (not used it - too new - IMO probably not enough compatible applications/drivers yet to be really useful), windows 8.1 I've only used on my phone, which is ok, but nothing spectacular, whereas Win7 is good in most respects - whether you can get a good deal on an upgrade is another matter though.
Probably best (if you can't get Firefox to work on Vista) to try another browser like Chrome or similar. Best of luck Doc.
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