Brakes mainly, Toyota used to (and may still be the case) strip clean and lube the brakes at every major service (around 20k), so every other year basically, so...pads out exercise the pistons to make sure they move freely, check the dust boots for deterioration, clean everything up and lube the sliding mechanism with the correct brake grease, don't forget to lube the handbrake cable and fittings, check flexible hoses for perishing and coat any exposed brake pipes with something like Castrol CL waterproof grease...up to you to decide if the brake fluid needs replacing.
Check drive shaft boots for splits and perishing, it is possible to regrease the joints but i'm one of the only people i know who does this.
Check auxilliary drive belt(s) carefully.
Whilst the car is jacked up spin the wheels and listen carefully for any odd sounds from the bearings, and check the various ball joints and suspension pivots.
Worth lubing the bonnet release cable/catch on any car, i also squirt a small amount of liquid grease into the keylocks, don't forget to lube sunroof if you have one.
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